(Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls

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dc.contributor.authorRoscales García, Silvia
dc.contributor.authorSánchez Sancho, Francisco
dc.contributor.authorGarcía Csákÿ, Aurelio
dc.date.accessioned2023-07-18T17:17:24Z
dc.date.available2023-07-18T17:17:24Z
dc.date.issued2023
dc.description.abstract(Ph3P)AuCl was discovered to be a powerful catalyst in the homocoupling of arylboronic acids and potassium aryltrifluoroborates for the synthesis of symmetrical biaryls. The reactions take place under benchtop reaction conditions in 96% EtOH at temperatures between rt and 50 °C with no exclusion of air or humidity, in the presence of F-TEDA (Selectfluor™) as an oxidant. The procedure is very functional group tolerant, and affords the corresponding biaryls in high yields with large substrate scope (26 examples).spa
dc.description.filiationUEMspa
dc.description.impact3.9 Q2 JCR 2023spa
dc.description.impact0.718 Q2 SJR 2023spa
dc.description.impactNo data IDR 2023spa
dc.description.sponsorshipMinistry of Science and Education, Spain (PID2021–124419NB-I00)spa
dc.identifier.citationRoscales, S., Sánchez-Sancho, F., & Csáky, A. G. (2023). (Ph3p)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls. Molecular Catalysis, 547, 113281. https://doi.org/10.1016/j.mcat.2023.113281spa
dc.identifier.doi10.1016/j.mcat.2023.113281
dc.identifier.issn2468-8231
dc.identifier.urihttp://hdl.handle.net/11268/12181
dc.language.isoengspa
dc.peerreviewedSispa
dc.relation.publisherversionhttps://doi.org/10.1016/j.mcat.2023.113281spa
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)spa
dc.rights.accessRightsopen accessspa
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.subject.otherÁcidos borónicosspa
dc.subject.unescoQuímica orgánicaspa
dc.subject.unescoAcidospa
dc.title(Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenylsspa
dc.typejournal articlespa
dspace.entity.typePublication

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