Nucleation and growth mechanism of polyfurane perchlorate doped films
| dc.contributor.author | González-Tejera, M. J. | |
| dc.contributor.author | Carrillo, Isabel | |
| dc.contributor.author | Hernández-Fuentes, Irmina | |
| dc.date.accessioned | 2016-09-23T15:04:39Z | |
| dc.date.available | 2016-09-23T15:04:39Z | |
| dc.date.issued | 2000 | |
| dc.description.abstract | The nucleation and growth mechanisms of polyfurane films doped with perchlorate anions (PFu/ClO4) were investigated on platinum electrodes in acetonitrile media. From the chronoamperometric response two different stages were distinguished, depending on applied overpotential and concentration conditions. At short times (t<to) the nucleation of the new phase was related to a diffusion-controlled process, and at longer times (t>to) the current was due to a mixture of progressive and instantaneous nucleation of small hemispherical nodules controlled by spherical diffusion. Three-dimensional growth was found. | spa |
| dc.description.filiation | UEM | spa |
| dc.description.impact | 1.597 JCR (2000) Q2, 7/16 Electrochemistry | spa |
| dc.description.sponsorship | Sin financiación | spa |
| dc.identifier.citation | González-Tejera, M. J., Carrillo Ramiro, I., & Hernández-Fuentes, Irmina. (2000). Nucleation and growth mechanism of polyfurane perchlorate doped films. Electrochimica Acta, 45(12), 1973-1982. DOI: 10.1016/S0013-4686(99)00416-8. | spa |
| dc.identifier.doi | 10.1016/S0013-4686(99)00416-8 | |
| dc.identifier.issn | 00134686 | |
| dc.identifier.uri | http://hdl.handle.net/11268/5809 | |
| dc.language.iso | eng | spa |
| dc.peerreviewed | Si | spa |
| dc.rights.accessRights | restricted access | en |
| dc.subject.uem | Electroquímica | spa |
| dc.subject.uem | Química física | spa |
| dc.subject.unesco | Electroquímica | spa |
| dc.subject.unesco | Química física | spa |
| dc.title | Nucleation and growth mechanism of polyfurane perchlorate doped films | spa |
| dc.type | journal article | spa |
| dspace.entity.type | Publication |