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dc.contributor.author | Abreu Silveira, Erick | |
dc.contributor.author | Moreno Pérez, Sonia | |
dc.contributor.author | Basso, Alessandra | |
dc.contributor.author | Serban, Simona | |
dc.contributor.author | Pestana Mamede, Rita | |
dc.contributor.author | Tardioli, Paulo W. | |
dc.contributor.author | Sánchez Farinas, Cristiane | |
dc.contributor.author | Rocha Martín, Javier | |
dc.contributor.author | Fernández Lorente, Gloria | |
dc.contributor.author | Guisan, José M. | |
dc.date.accessioned | 2018-01-02T19:04:37Z | |
dc.date.available | 2018-01-02T19:04:37Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Silveira, E. A., Moreno-Perez, S., Basso, A., Serban, S., Mamede, R. P., Tardioli, P. W., ... & Guisan, J. M. (2017). Modulation of the regioselectivity of Thermomyces lanuginosus lipase via biocatalyst engineering for the Ethanolysis of oil in fully anhydrous medium. BMC Biotechnology, 17, 1-13. DOI: 10.1186/s12896-017-0407-9 | spa |
dc.identifier.issn | 1472-6750 | |
dc.identifier.uri | http://hdl.handle.net/11268/6935 | |
dc.description.abstract | Enzymatic ethanolysis of oils (for example, high oleic sunflower oil containing 90% of oleic acid) may yield two different reaction products depending on the regioselectivity of the immobilized lipase biocatalyst. Some lipase biocatalysts exhibit a 1,3-regioselectivity and they produced 2 mols of fatty acid ethyl ester plus 1 mol of sn2-monoacylglycerol (2-MAG) per mol of triglyceride without the release of glycerol. Other lipase biocatalysts are completely non-regioselective releasing 3 mols of fatty acid ethyl ester and 1 mol of glycerol per mol of triglyceride. Lipase from Thermomyces lanuginosus (TLL) adsorbed on hydrophobic supports is a very interesting biocatalyst for the ethanolysis of oil. Modulation of TLL regioselectivity in anhydrous medium was intended via two strategies of TLL immobilization: a. - interfacial adsorption on different hydrophobic supports and b.- interfacial adsorption on a given hydrophobic support under different experimental conditions. | spa |
dc.description.sponsorship | Spanish Ministry of Economy, Industry and Competitiveness (projects BIO2012–36861 and CTQ2015–70348) | spa |
dc.description.sponsorship | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | spa |
dc.language.iso | eng | spa |
dc.title | Modulation of the regioselectivity of Thermomyces lanuginosus lipase via biocatalyst engineering for the Ethanolysis of oil in fully anhydrous medium | spa |
dc.type | article | spa |
dc.description.impact | 2.605 JCR (2017) Q2, 62/160 Biotechnology and Applied Microbiology | spa |
dc.identifier.doi | 10.1186/s12896-017-0407-9 | |
dc.rights.accessRights | openAccess | spa |
dc.subject.uem | Biodiesel | spa |
dc.subject.unesco | Enzima | spa |
dc.subject.unesco | Energía de la biomasa | spa |
dc.description.filiation | UEM | spa |
dc.peerreviewed | Si | spa |